168642-00-0

Upstream product

• 591-81-1 4-hydroxybutanoic acid 
• 128143-89-5 4'-Chloro-2,2':6',2''-terpyridine 

Downstream Products

• 209916-07-4 N-[2-(4,4'-dimethoxytrityl)-1-(hydroxymethyl)ethyl]-4-(2,2':6',2-terpyridin-4'-yloxy)butyramide 
• 910227-82-6 4-[bis-(4-methoxy-phenyl)-phenyl-methoxy]-2-hydroxy-3,3-dimethyl-N-{3-[4-([2,2';6',2'']terpyridin-4'-yloxy)-butyrylamino]-propyl}-butyramide 
• 913081-77-3 N-{2-[bis-(4-methoxy-phenyl)-phenyl-methoxy]-1-hydroxymethyl-ethyl}-4-([2,2';6',2'']terpyridin-4'-yloxy)-butyramide 

Relevant academic research and scientific papers

Terpyridyl derivatives as bifunctional chelates: Synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′:6′,2″- terpyridine and chloro(4′-methylsulfanyl-2,2′:6′,2″-terpyridine) gold(III) bis(trifluoromethanesulfonate)

A variety of 2,2′:6′,2″-terpyridine (terpy) derivatives modified at the 4′ position has been synthesized to generate bifunctional chelates. A particularly convenient route to these bifunctional chelates, based on nucleophilic substitution of 4′-chloroterpyridine is described. The crystal structure of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′:6′,2″- terpyridine has been determined. The palladium(III) and gold(III) complexes of the analog with an SMe group at the 4′ position have been synthesized and characterized. The crystal structure of the latter has been determined.

Nanometric dendritic macromolecules: Stepwise assembly by double (2,2′: 6′,2″-terpyridine)ruthenium(I) connectivity

The construction of nanometric, dendritic macromolecules by bis(2,2′: 6′,2″-terpyridine)ruthenium(II) connectivity is investigated. The assembly methodology, which incorporates both the control of metal complexation sites and degree of flexibility within the linkages, has been demonstrated.

Wege zu dendritischen Netzwerken: Bis-Dendrimere durch Verknuepfung von Kaskadenmolekuelen ueber Metallzentren

Keywords: Dendrimere; Elektrochemie; Makromolekuele; Rutheniumverbindungen