168698-30-4Relevant academic research and scientific papers
Preparation of silver nanoparticles from silver(I) nano-coordination polymer
Akhbari, Kamran,Morsali, Ali
, p. 1435 - 1440 (2010)
Nanorods of two-dimensional organometallic coordination polymer, [Ag(μ4-DPOAc)]n (1) [DPOAc- = diphenylacetate], has been synthesized by the reaction of potassium diphenylacetate (DPOAcK) and AgNO3 by sonochemic
Unique Ag-C bonds, thermal, fluorescence, structural and solution studies of two-dimensional silver(I) coordination polymer
Akhbari, Kamran,Morsali, Ali,Zeller, Matthias
, p. 3788 - 3795 (2007)
A 2D polymer with unique Ag-C bonds, [Ag(μ4-DPOAc)]n (1) [DPOAc = diphenylacetate], has been synthesized and characterized and its structure was determined by X-ray crystallography. In addition to the coordination to the O atoms of DPOAc the Ag atoms also form strong η1 Ag-C π bonds and exhibit weak Ag-Ag interactions, resulting in the formation of O3 CAg ? AgO3 C moieties. The thermal stabilities of 1 and of its thallium(I) analogue, [Tl(μ3-DPOAc)]n (2), were studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The ligand and compounds 1-2 are luminescent in the solution state, with emission maxima at 370, 383 and 360 nm, respectively. The results of studies of the stoichiometry and formation of complexes of 1 and 2 in DMF solution were found to be in support of their solid state stoichiometry.
Reaction of Tp(PPh3)Ru(η2-O2CCHPh2) with carbene and vinylidene precursors
Sanford, Melanie S.,Valdez, Michelle R.,Grubbs, Robert H.
, p. 5455 - 5463 (2008/10/08)
Tp(PPh3)Ru(η2-O2CCHPh2) (1) [Tp = tris(pyrazolyl)borate] has been prepared by the reaction of TpRu(Cl)(PPh3)2 with 1.2 equiv of NaO2CCHPh2. Complex 1 reacts with diphe
