16889-10-4Relevant articles and documents
Stable diazonium salts of weakly basic amines—Convenient reagents for synthesis of disperse azo dyes
Qiu, Jinjing,Tang, Bingtao,Ju, Benzhi,Xu, Yuanji,Zhang, Shufen
, p. 63 - 69 (2016/08/24)
A new synthetic strategy for industrially important deep-shade disperse azo dyes was presented in this study. The key procedure is to prepare stable solid diazonium salts of weakly basic amines in the absence of concentrated sulfuric acid. Diazotization by tert-butyl nitrite in ethyl acetate was allowed to proceed in the presence of equivalent 1,5-naphthalenedisulfonic acid as stabilizer of diazonium salts and donor of hydrogen ion for the reaction. The separated solid diazonium salts exhibited good thermal stability. The corresponding disperse azo dyes were subsequently synthesized through the azo-coupling of the prepared solid diazonium salts with a range of aromatic tertiary amines. The azo dyes were produced in short reaction time, excellent yields, mild reaction conditions, simple experimental procedure and low energy consumption.
EFFECT OF BENZANNELLATION ON THE COLOR OF p-AMINOAZO COMPOUNDS
Gorelik, M. V.,Lomzakova, V. I.
, p. 1641 - 1646 (2007/10/02)
Monoazo dyes containing a naphthalene ring were obtained by diazotization of 1-amino-4-nitro-2-naphthonitrile, 3-amino-5-nitronaphthoisothiazole, and 3-amino-5-nitrobenzoindazole and coupling of the diazonium salts with N,N-dialkyl derivatives of anilines.Their visible spectra were compared with the spectra of the corresponding benzene analogs.Annellation of the benzene ring in the residue of the diazo component gives rise to a bathochromic or hypsochromic shift, depending on the structure of the dye.The nature of the observed effects is discussed.
