Cas 168961-28-2,(1S,2R,4S,6S,7R)-4-((S)-1-Hydroxy-1-phenyl-propyl)-7,10,10-trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0<sup>2,6</sup>]decane-5-carboxylic acid tert-butyl ester

168961-28-2

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Basic information

Product Name: (1S,2R,4S,6S,7R)-4-((S)-1-Hydroxy-1-phenyl-propyl)-7,10,10-trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decane-5-carboxylic acid tert-butyl ester
Synonyms:
CAS NO:168961-28-2
Molecular Formula:
Molecular Weight: 415.573
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (1S,2R,4S,6S,7R)-4-((S)-1-Hydroxy-1-phenyl-propyl)-7,10,10-trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decane-5-carboxylic acid tert-butyl ester(CAS DataBase Reference)
NIST Chemistry Reference: (1S,2R,4S,6S,7R)-4-((S)-1-Hydroxy-1-phenyl-propyl)-7,10,10-trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decane-5-carboxylic acid tert-butyl ester(168961-28-2)
EPA Substance Registry System: (1S,2R,4S,6S,7R)-4-((S)-1-Hydroxy-1-phenyl-propyl)-7,10,10-trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decane-5-carboxylic acid tert-butyl ester(168961-28-2)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 168961-28-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 168961-28-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,8,9,6 and 1 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 168961-28:
(8*1)+(7*6)+(6*8)+(5*9)+(4*6)+(3*1)+(2*2)+(1*8)=182
182 % 10 = 2
So 168961-28-2 is a valid CAS Registry Number.

168961-28-2Upstream product

168784-77-8 (1S,2R,4S,6S,7R)-7,10,10-Trimethyl-4-propionyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decane-5-carboxylic acid tert-butyl ester

168961-28-2Downstream Products

69489-15-2 (S)-(-)-hydroxy-2-phenylbutanal

168961-28-2Relevant academic research and scientific papers

Camphor-derived 2-stannyl-N-Boc-1,3-oxazolidine: A new chiral formylanion equivalent for the asymmetric synthesis of 1,2-diols

Colombo, Lino

, p. 2863 - 2866 (2007/10/02)

Optically pure 2-tributylstannyl-N-Boc-1,3-oxazolidine 6, prepared from the camphor-derived aminoalcohol 5, was converted to diastereomerically pure 2-acyl derivatives 8 in three steps. Reaction of these ketones with Grignard reaagents at -78°C proceeded with high stereoselectivity affording tertiary carbinols which gave 1,2-diols with >96% ee after hydrolysis and reduction of the intermediate α-hydroxy aldehydes. A new deblocking procedure of the t-Boc group is also described.

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