169129-44-6Relevant articles and documents
Synthesis and reactivity of a 3-vinylidenepiperidine as a model study of α-allenic amines
Solé, Daniel,García-Rubio, Silvina,Bosch, Joan,Bonjoch, Josep
, p. 2415 - 2424 (2007/10/03)
4-Acetonyl-1-benzyl-3-vinylidenepiperidine (8), prepared by cyclization of propargylic silane (7), was used as a model to study the usefulness of the allene moiety as a precursor of the two-carbon chain present in the piperidine ring of Strychnos alkaloids.
Tandem Michael reactions for the construction of pyrrolidine and piperidine ring systems
Barco,Benetti,Casolari,Pollini,Spalluto
, p. 3039 - 3042 (2007/10/02)
A convergent one-pot construction of disubstituted pyrrolidine and piperidine frameworks has been accomplished through a simple protocol involving intermolecular conjugate addition of a nitrogen nucleophile to an electrophilic olefin followed by intramolecular trapping of the generated enolate by a built-in α,β-unsaturated acceptor.