169138-22-1Relevant academic research and scientific papers
Intramolecular polar addition reactions of active methylene moieties to aryl-substituted alkenes via photoinduced electron transfer
Ohashi, Maki,Nakatani, Keisuke,Maeda, Hajime,Mizuno, Kazuhiko
supporting information; scheme or table, p. 5537 - 5539 (2010/11/03)
The synthesis of cycloalkane derivatives with ring sizes of 5-7 was achieved in moderate yields by photoirradiation of aqueous acetonitrile solutions, containing compounds that consist of active methylene moieties tethered to aryl-substituted alkenes along with sodium hydroxide and 9-cyanophenanthrene. When the substrate contains ethyl cyanoacetate as an asymmetric active methylene moiety, the reaction proceeds in a highly diastereoselective manner.
Efficient production of enol ether radical cations by heterolytic cleavage of β-mesylate radicals
Taxil, Elsa,Bagnol, Laurent,Horner, John H.,Newcomb, Martin
, p. 827 - 830 (2007/10/03)
(Matrix presented) α-Methoxy-β-mesyloxy radicals were produced in laser flash photolysis reactions, and yields of enol ether radical cations formed by heterolytic fragmentation of the mesylate group were determined. The mesylate heterolysis reaction is fa
