503073-55-0Relevant academic research and scientific papers
Efficient production of enol ether radical cations by heterolytic cleavage of β-mesylate radicals
Taxil, Elsa,Bagnol, Laurent,Horner, John H.,Newcomb, Martin
, p. 827 - 830 (2007/10/03)
(Matrix presented) α-Methoxy-β-mesyloxy radicals were produced in laser flash photolysis reactions, and yields of enol ether radical cations formed by heterolytic fragmentation of the mesylate group were determined. The mesylate heterolysis reaction is fa
Laser flash photolysis kinetic studies of enol ether radical cations. Rate constants for heterolysis of α-methoxy-β-phosphatoxyalkyl radicals and for cyclizations of enol ether radical cations
Horner, John H.,Taxil, Elsa,Newcomb, Martin
, p. 5402 - 5410 (2007/10/03)
Two series of enol ether radical cations were studied by laser flash photolysis methods. The radical cations were produced by heterolyses of the phosphate groups from the corresponding α-methoxy-β-diethylphosphatoxy or β-diphenylphosphatoxy radicals that
