1692-39-3

Usage

Uses

Used in Organic Synthesis:
Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, cisis employed as a key intermediate in organic synthesis for the production of various chemical compounds. Its unique structure and aromatic properties make it a valuable building block in the synthesis of complex organic molecules.
Used in Pharmaceutical Production:
Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, cisis utilized in the manufacturing process of certain pharmaceuticals. Its specific chemical structure allows it to be incorporated into the molecular frameworks of drugs, potentially enhancing their therapeutic effects or improving their pharmacokinetic properties.
Used in Agrochemicals:
Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, cisis also used in the development of agrochemicals, such as pesticides and herbicides. Its chemical properties can contribute to the effectiveness of these products in controlling pests and weeds in agricultural settings.
Used in Research and Development:
Due to its unique structure and properties, Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, cis- serves as a subject of interest in research and development within the chemical and pharmaceutical industries. It may be studied for its potential applications in new drug discovery or for improving existing chemical processes.

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 824-94-2 p-methoxybenzyl chloride 
• 637-69-4 4-Methoxystyrene 
• 1433968-04-7 C₄₈H₆₀AuN₄O₃S⁽¹⁺⁾*CF₃O₃S^(1-) 
• 1433968-01-4 1-mesityl-2-((4-methoxybenzyl)sulfonyl)-3-methyl-1H-imidazolium trifluoromethanesulfonate 
• 1433968-06-9 1-mesityl-2-((4-methoxybenzyl)thio)-1H-imidazole 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 29304-87-8 7-(4-methoxyphenyl)cyclohepta-1,3,5-triene 
• 2373-89-9 4,4'-dimethoxychalcone 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Downstream Products

• 109423-43-0 C₃₃H₂₆N₂O₂ 
• 109423-43-0 C₃₃H₂₆N₂O₂ 
• 52751-67-4 3,5-bis-(4-methoxyphenyl) isoxazole 
• 96908-14-4 4-nitro-3,5-di(p-methoxyphenyl)isoxazole 
• 6000-10-8 trans-1,2-bis(4-methoxyphenyl)cyclopropane 
• 104-87-0 4-methyl-benzaldehyde 
• 86396-75-0 1,3-bis(4-methylphenyl)-1-hydroxy-3-propanone 
• 122-00-9 para-methylacetophenone 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 139067-26-8 trans-1,2-di(4-methoxyphenyl)cyclopropane 
• 86396-68-1 cis-3,5-bis(4-methoxyphenyl)-1,2-dioxolane 
• 20821-99-2 3,5-Bis(p-methoxyphenyl)-4,5-dihydroisoxazole 
• 112430-01-0 cis-3,5-di(4-methoxyphenyl)-1,2-oxathiolane (2,3)-trans-2-oxide 

Relevant academic research and scientific papers

1,3-Oxyalkynylation of Aryl Cyclopropanes with Ethylnylbenziodoxolones Using Photoredox Catalysis

Alkynes and cyclopropanes are vital motifs in chemistry. Herein, a photoredox catalyzed 1,3-oxyalkynylation of aryl cyclopropanes with ethylnylbenziodoxolones (EBXs) in an atom-economic fashion is described. This cascade comprises single-electron oxidatio

Rational design of a gold carbene precursor complex for a catalytic cyclopropanation reaction

Bridging gas- and solution-phase chemistry: A gold(I) carbene precursor complex has been developed and investigated for catalytic cyclopropanation. Formation of the carbene intermediate was first probed by mass spectrometry, followed by cyclopropanation of p-methoxystyrene in solution. The imidazolylidene leaving group serves as a base generated in situ that is necessary in the putative catalytic cycle. Copyright

Cyclopropanation with gold(I) carbenes by retro-Buchner reaction from cycloheptatrienes

Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes.

Redox-photosensitized aminations of 1,2-benzo-1,3-cycloalkadienes, arylcyclopropanes, and quadricyclane with ammonia

1,2,4-Triphenylbenzene and 2,2′-methylenedioxy-1,1′ -binaphthalene successfully photosensitized the aminations of 1,2-benzo-1,3-cycloalkadienes, arylcyclopropanes, and quadricyclane with ammonia and primary amines in the presence of m- or p-dicyanobenzene, which gave the 4-amino-1,2-benzocycloalkenes, 3-amino-1-arylpropanes, and 7-amino-5-(p-cyanophenyl)bicyclo[2.2.1]hept-2-ene, respectively. A key pathway for the photosensitized amination is the hole transfer from the cation radicals of the sensitizers that were generated by photoinduced electron transfer to the electron acceptors to the substrates. Therefore, it was found that the relationships in oxidation potentials between the sensitizers and the substrates and the positive charge distribution of the cation radicals of the substrates were important factors for the efficient amination.

Kinetic Study of the Homolytic Brominolysis of 1,2-Diarylcyclopropanes

The rate constants for the photolytic brominolysis of 22 trans-1,2-diarylcyclopropanes in carbon disulfide relative to an internal standard, p-chlorotoluene, have been determined.The products of the brominolysis are 1,3-dibromo-1,3-diarylpropanes.The rate constants range over 5 orders of magnitude, being enhanced by electrondonating substituents on one or both benzene rings.The quantitative size of the substituent effect (ρ) at either involved carbon center is a function of the substituent at the other center.This fact suggests a continuum of transition-state structures with varying degrees of bond breaking and charge separation.