169298-79-7Relevant academic research and scientific papers
A directed amidohalogenation reaction. An unusual reaction of azidoformates
Bergmeier,Stanchina
, p. 4533 - 4536 (1995)
The thermal intramolecular reaction of an azidoformate and an olefin does not provide the expected aziridine, but rather an amidohalide. This unusual product is formed via an intramolecular nitrene addition to the olefin to initially provide an aziridine.
Synthesis of Vicinal Amino Alcohols via a Tandem Acylnitrene Aziridination-Aziridine Ring Opening
Bergmeier, Stephen C.,Stanchina, Dionne M.
, p. 4449 - 4456 (2007/10/03)
A facile synthesis of differently substituted vicinal amino alcohols is reported. We have demonstrated that these amino alcohols could be readily prepared from the oxazolidinones by treatment with aqueous base. We have synthesized a variety of substituted
