169302-13-0Relevant academic research and scientific papers
Synthesis, structure, and reactivity of [Cu(phen)2]ClO 2: Aerobic oxidation of Cl- to ClO2- at room temperature
Hossain, Md. Munkir,Tseng, Mei-Chun,Lee, Chi-Rung,Shyu, Shin-Guang
, p. 36 - 40 (2014)
An unusual 4e- oxidation of Cl- into ClO 2- occurred during the reaction between CuCl and phenanthroline (phen) in air to form a [Cu(phen)2]ClO2 complex, which is capable of oxidizing catechol into the highly substituted pentenone derivative methyl 1-hydroxy-2-oxo-4,5,5-trimethoxycyclopent-3-ene-1- carboxylate through contraction of the aromatic ring by extradiol C-C bond cleavage concomitant with the further formation of a C-C bond. Copyright
Synthesis, structure, and reactivity of [Cu(phen)2]ClO2: Aerobic oxidation of Cl- to ClO2- at room temperature
Hossain, Md. Munkir,Tseng, Mei-Chun,Lee, Chi-Rung,Shyu, Shin-Guang
, p. 36 - 40 (2015/04/27)
An unusual 4e- oxidation of Cl- into ClO2- occurred during the reaction between CuCl and phenanthroline (phen) in air to form a [Cu(phen)2]ClO2 complex, which is capable of oxidizing catechol into the highly substituted pentenone derivative methyl 1-hydroxy-2-oxo-4,5,5-trimethoxycyclopent-3-ene-1-carboxylate through contraction of the aromatic ring by extradiol C-C bond cleavage concomitant with the further formation of a C-C bond. The copper(II)-catalyzed aerobic oxidation of Cl- to ClO2- to form the [Cu(phen)2]ClO2 (phen = phenanthroline) complex at room temperature is reported. The oxidation of catechol by using [Cu(phen)2]ClO2 yields methyl 1-hydroxy-2-oxo-4,5,5-trimethoxycyclopent-3-ene-1-carboxylate including 4,5-dimethoxy-1,2-benzoquinone
