169330-16-9Relevant academic research and scientific papers
Boron-Promoted Ether Interchange Reaction: Synthesis of Alkyl Nitroaromatic Ethers from Methoxynitroarenes
Liu, Zhenwei,Luan, Nannan,Lu, Hongtao,Liang, Apeng,Li, Jingya,Zou, Dapeng,Wu, Yangjie,Wu, Yusheng
, p. 702 - 707 (2020/02/11)
The first protocol for boron-promoted ether interchange reaction of methoxynitroarenes was described. A series of methoxynitroarenes and alcohols, including primary, secondary, as well as tertiary alcohols were reacted smoothly in moderate to good yields under the optimized reaction conditions. This protocol constitutes an operationally simple and scalable strategy for the synthesis of alkyl nitroaromatic ethers. Moreover, the new reactivity of boron reagents was discovered.
Trapping of translocated radicals by tetrathiafulvalene radical cation
Murphy, John A.,Roome, Stephen J.
, p. 1349 - 1358 (2007/10/02)
Aryl radicals are generated by electron transfer from tetrathiafulvalene to arenediazonium salts.The aryl radicals are translocated into alkyl radicals which undergo a C-S or C-C bond formation to tetrathiafulvalene radical cation, depending on the nucleophilicity/electrophilicity of the translocated carbon radical.
