169438-00-0

Basic information

• Product Name: Acetic acid (1S,5S)-3-ethynyl-5-hydroxy-4-methyl-cyclohex-3-enyl ester
• Synonyms: Acetic acid (1S,5S)-3-ethynyl-5-hydroxy-4-methyl-cyclohex-3-enyl ester
• CAS NO: 169438-00-0
• Molecular Weight: 194.23
• Mol File: 169438-00-0.mol

Chemical Properties

• CAS DataBase Reference: Acetic acid (1S,5S)-3-ethynyl-5-hydroxy-4-methyl-cyclohex-3-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (1S,5S)-3-ethynyl-5-hydroxy-4-methyl-cyclohex-3-enyl ester(169438-00-0)
• EPA Substance Registry System: Acetic acid (1S,5S)-3-ethynyl-5-hydroxy-4-methyl-cyclohex-3-enyl ester(169438-00-0)

Safety Data

• Hazardous Substances Data: 169438-00-0(Hazardous Substances Data)

Upstream product

• 169305-52-6 (5S)-3-Ethynyl-5-hydroxy-2-methyl-2-cyclohexen-1-one 
• 146728-48-5 (3R,5S)-3,5-dihydroxy-1-ethynyl-2-methylcyclohex-1-ene 
• 108-05-4 vinyl acetate 
• 169437-96-1 (3S,5S)-1-ethynyl-3,5-dihydroxy-2-methylcyclohex-1-ene 

Downstream Products

• 169437-96-1 (3S,5S)-1-ethynyl-3,5-dihydroxy-2-methylcyclohex-1-ene 

Relevant articles and documents

Selective acylation of A-ring precursors of vitamin D using enzymes in organic solvents

Whereas Chromobacterium viscosum lipase (CVL) catalyzes selectively the acylation of the C-5 hydroxyl of the three stereoisomeric vitamin D A-ring precursors 2a, 3a and 3b, only the C-3 hydroxyl of the fourth stereoisomer 2b is acylated under the same conditions in organic solvent. In a convenient application, the racemic vitamin D A-ring precursor 4, possessing only the C-5 hydroxyl, was resolved using suitable conditions identified from the studies of 2 and 3.