169514-07-2Relevant academic research and scientific papers
Easy Synthesis and Different Conformational Behavior of Purine and Pyrimidine β-D-glycero-Pent-2'-enopyranosyl Nucleosides
Doboszewski, Bogdan,Blaton, Norbert,Herdewijn, Piet
, p. 7909 - 7919 (1995)
Condensation of 3,4-bis-O-(p-nitrobenzoyl)-D-xylal with purines and pyrimidines (A, C, 6-chloropurine, G, T, U) without externally added acid catalyst leads to the 2',3'-unsaturated pentopyranosyl nucleosides in preparatively acceptable yields of both β a
Synthesis of the β-2',3'-unsaturated pentopyranosyl nucleosides and their 3'-hydroxymethyl congeners
Doboszewski,Blaton,Herdewijn
, p. 317 - 320 (2007/10/02)
Fusion of the glycal 3 and purines/pyrimidines without acid catalyst provides anomeric mixtures of the 2',3'-unsaturated pentopyranosyl nucleosides 4, which have been worked out to furnish the 3'-hydroxymethyl analogues, e.g. 5.
