169524-62-3Relevant academic research and scientific papers
Chiral N-heterocyclic carbene-copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides: Steric and electronic effects on γ-selectivity
Selim, Khalid B.,Nakanishi, Hirotsugu,Matsumoto, Yasumasa,Yamamoto, Yasutomo,Yamada, Ken-Ichi,Tomioka, Kiyoshi
experimental part, p. 1398 - 1408 (2011/04/25)
Chiral N-heterocyclic carbene ligands were electronically and sterically tuned to improve γ-selectivity in copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides with several aryl Grignard reagents. High γ-selectivity was realized
Arylations of allylic acetates with triarylbismuths as atom-efficient multi-coupling reagents under palladium catalysis
Rao, Maddali L.N.,Banerjee, Debasis,Giri, Somnath
scheme or table, p. 5757 - 5761 (2009/12/24)
Arylation of allylic acetates employing triarylbismuths as multi-coupling reagents under palladium-catalyzed conditions was reported. Triarylbismuths as nucleophilic coupling partners were used in sub-stoichiometric amounts with respect to allylic acetate
