131665-81-1Relevant articles and documents
Highly selective hydrosilylation of equilibrating allylic azides
Liu, Ruzhang,Liu, Yongmei,Wang, Juan,Wei, Zhen,Xue, Huaiguo
supporting information, p. 5038 - 5041 (2020/05/18)
The Pt-catalyzed hydrosilylation of equilibrating allylic azides is reported. The reaction provides only one out of four possible hydrosilylation products in good yields and with very high chemoselectivity (alk-1-enevs.alk-2-ene), regioselectivity (linearvs.branched), and excellent functional group tolerance.
Copper-catalyzed vinylsilane allylation
Cornelissen, Loic,Vercruysse, Sebastien,Sanhadji, Ayoub,Riant, Olivier
supporting information, p. 35 - 38 (2014/01/06)
Soft reaction conditions, particularly important in total synthesis, have dragged many researchers into the field of silylated organic compounds. Hereby, we describe a new copper-catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using a copper(I) salt, and this led to the formation of polysubstituted 1,4-dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. Hereby is described a new copper-catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using copper(I) salts, and this led to the formation of polysubstituted 1,4-dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. TBAT = tetrabutylammonium difluorotriphenylsilicate. Copyright
Negative inotropic and calcium antagonistic activity of alkyl and arylalkyl phosphonates
Bellucci,Gualtieri,Scapecchi,Teodori,Budriesi,Chiarini
, p. 1167 - 1191 (2007/10/02)
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