16956-91-5Relevant articles and documents
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Fearon,F.W.G.,Gilman,H.
, p. 535 - 537 (1967)
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REACTIONS OF POLYFLUORO AROMATIC COMPOUNDS WITH ELECTROPHILIC AGENTS IN THE PRESENCE OF TRIS(DIALKYLAMINO)PHOSPHINES. I. SYNTHESIS OF TRIALKYLSILYL(GERMYL, STANNYL, OR PLUMBYL)POLYFLUOROBENZENES
Bardin, V. V.,Pressman, L. S.,Rogoza, L. N.,Furin, G. G.
, p. 1931 - 1937 (2007/10/02)
Polyfluorophenyl bromides and iodides react with alkylhalo derivatives of silicon, germanium, tin, or lead in the presence of equimolar amounts of a tris(dialkylamino)phosphine to give polyfluorophenyl(alkyl) derivatives of the above-mentioned elements and phosphonium salts.Electron-donor substituents in position 4 of the polyfluorophenyl bromide slow down the reaction, while electron-acceptor substituents accelerate it.