169563-55-7

Upstream product

• 103477-58-3 2-(2-bromo-4,5-dimethoxyphenyl)-1,3-dioxolane 
• 169563-54-6 (2-[1,3]Dioxolan-2-yl-4,5-dimethoxy-phenyl)-trimethyl-silane 

Downstream Products

• 169563-58-0 1-(tert-Butyldimethylsiloxy)-2-cyclopropylidene-2-(4,5-dimethoxy-2-(trimethylsilyl)phenyl)ethane 
• 169563-57-9 (tert-Butyldimethylsiloxy)methyl 4,5-dimethoxy-2-(trimethylsilyl)phenyl ketone 
• 1026036-34-9 1-[1-(tert-Butyl-dimethyl-silanyloxy)-vinyl]-4,5-dimethoxy-2-trimethylsilanyl-benzene 
• 169563-59-1 2-Cyclopropylidene-2-(4,5-dimethoxy-2-(trimethylsilyl)phenyl)ethanol 
• 169563-56-8 4-Acetyl-5-(trimethylsilyl)veratrole 
• 213984-29-3 N-(4,5-Dimethoxy-2-trimethylsilanyl-benzyl)-2,2,2-trifluoro-N-[2-(4-hydroxy-phenyl)-ethyl]-acetamide 
• 1027169-57-8 1-(4,5-Dimethoxy-2-trimethylsilanyl-phenyl)-ethanol 

Relevant academic research and scientific papers

A Highly Enantiocontrolled Strategy for the Synthesis of Benzylic Quaternary Carbon Centers. A Formal Total Synthesis of (-)-Mesebrine

A remarkable substituent effect by a trimethylsilyl group was observed on the enantioselectivity of the tandem asymmetric epoxidation and enantiospecific ring expansion of 2-cyclopropylidene-2-(4,5-dimethoxy-2-(trimethylsilyl)phenyl)ethanol (24), affordin

Oxidative Intramolecular Phenolic Coupling Reaction Induced by a Hypervalent Iodine(III) Reagent: Leading to Galanthamine-Type Amaryllidaceae Alkaloids

By extending our oxidative phenol-coupling reactions using a hypervalent iodine(III) reagent, a versatile synthetic procedure for the galanthamine-type Amaryllidaceae alkaloids was accomplished. The first total synthesis of (±)-sanguinine and the total syntheses of (±)-galanthamine, (±)- narwedine, (±)-lycoramine, and (±)-norgalanthamine were also successfully carried out.