A Highly Enantiocontrolled Strategy for the Synthesis of Benzylic Quaternary Carbon Centers. A Formal Total Synthesis of (-)-Mesebrine

DOI: 10.1021/jo00126a030

Source and publish data:

Journal of Organic Chemistry p. 6785 - 6790 (1995)

Update date:2022-08-03

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Authors:

Nemoto, Hideo

Tanabe, Tetsuro

Fukumoto, Keiichiro

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Article abstract of DOI:10.1021/jo00126a030

A remarkable substituent effect by a trimethylsilyl group was observed on the enantioselectivity of the tandem asymmetric epoxidation and enantiospecific ring expansion of 2-cyclopropylidene-2-(4,5-dimethoxy-2-(trimethylsilyl)phenyl)ethanol (24), affordin

Full text of DOI:10.1021/jo00126a030

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