1696-31-7Relevant academic research and scientific papers
POLYFLUOROCYCLOALKENES. PART XVI . SOME ADDITION REACTIONS OF 1-TRIFLUOROMETHYLNONAFLUOROCYCLOHEX-1-ENE
Carter, Paul A.,Patrick, Colin R.,Tatlow, John Colin
, p. 407 - 412 (1982)
Reactions with alcohols and base repleaced the vinylic fluorine of 1-trifluoromethylnonafluorocyclohex-1-ene (I) by methoxy and ethoxy groups.Fluorination with cobaltic fluoride gave, from the former, a number of saturated polyfluoro-ethers.Oxidation of the alkoxy-cycloalkenes gave hexafluoroglutaric acid.Cycloalkene I gave with ammonia an imino-enamine, which was hydrolysed by dilute acid to a keto-enamine.I was defluorinated by heated iron to octafluorotoluene.
