POLYFLUOROCYCLOALKENES. PART XVI . SOME ADDITION REACTIONS OF 1-TRIFLUOROMETHYLNONAFLUOROCYCLOHEX-1-ENE

DOI: 10.1016/S0022-1139(00)81453-0

Source and publish data:

Journal of Fluorine Chemistry p. 407 - 412 (1982)

Update date:2022-08-03

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Authors:

Carter, Paul A.

Patrick, Colin R.

Tatlow, John Colin

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Article abstract of DOI:10.1016/S0022-1139(00)81453-0

Reactions with alcohols and base repleaced the vinylic fluorine of 1-trifluoromethylnonafluorocyclohex-1-ene (I) by methoxy and ethoxy groups.Fluorination with cobaltic fluoride gave, from the former, a number of saturated polyfluoro-ethers.Oxidation of the alkoxy-cycloalkenes gave hexafluoroglutaric acid.Cycloalkene I gave with ammonia an imino-enamine, which was hydrolysed by dilute acid to a keto-enamine.I was defluorinated by heated iron to octafluorotoluene.

Full text of DOI:10.1016/S0022-1139(00)81453-0

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