Journal of Fluorine Chemistry p. 407 - 412 (1982)
Update date:2022-08-03
Topics:
Carter, Paul A.
Patrick, Colin R.
Tatlow, John Colin
Reactions with alcohols and base repleaced the vinylic fluorine of 1-trifluoromethylnonafluorocyclohex-1-ene (I) by methoxy and ethoxy groups.Fluorination with cobaltic fluoride gave, from the former, a number of saturated polyfluoro-ethers.Oxidation of the alkoxy-cycloalkenes gave hexafluoroglutaric acid.Cycloalkene I gave with ammonia an imino-enamine, which was hydrolysed by dilute acid to a keto-enamine.I was defluorinated by heated iron to octafluorotoluene.
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