169618-84-2

Usage

Uses

Used in Pharmaceutical Industry:
[1,1':3',1''-Terphenyl]-2'-carboxaldehyde is used as a building block for the synthesis of various organic molecules, including pharmaceuticals, due to its unique structure and properties.
Used in Dye Industry:
[1,1':3',1''-Terphenyl]-2'-carboxaldehyde is used as a component in the production of dyes, taking advantage of its chemical properties.
Used in Polymer Industry:
[1,1':3',1''-Terphenyl]-2'-carboxaldehyde is used in the synthesis of polymers, contributing to the development of new materials with specific characteristics.
Used in Optoelectronic Devices and Materials:
[1,1':3',1''-Terphenyl]-2'-carboxaldehyde is used as a potential component in the field of optoelectronic devices and materials, thanks to its photoactive properties.

Upstream product

• 108-86-1 bromobenzene 
• 1613-90-7 4-methoxy-N-[(E)-phenylmethylidene]aniline 
• 17099-11-5 N-(4-methoxyphenyl)-2-chlorobenzylidenimine 
• 100-58-3 phenylmagnesium bromide 
• 38018-60-9 (E/Z)-2-bromo-4'-methoxystilbene 
• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 3369-37-7 N-(o-methoxybenzylidene)aniline 
• 38018-61-0 1-(2-methoxyphenyl)-N-(4-methoxyphenyl)methanimine 
• 13033-50-6 N-(2-methoxybenzylidene)isopropylamine 
• 17680-04-5 (3,4-methylenedioxy)phenylmagnesium bromide 

Downstream Products

• 1352211-32-5 triisopropyl(8-phenyl-5H-dibenzo[a,c][7]annulen-6-yl)silane 
• 5501-35-9 1-phenyl-9H-fluoren-9-one 

Relevant academic research and scientific papers

Modular Arene Difunctionalization of Unactivated C-O and C-H Bonds by Sequential Chromium-Catalyzed Transformations

Sequential transformations of unactivated C-O and C-H bonds under chromium catalysis are described. The use of a N-benzyl-substituted imino group as an auxiliary combined with chromium(II) chloride as a precatalyst and 2,3-dichlorobutane as an oxidant allows the arene C-O and C-H bonds to sequentially couple to arylmagnesium reagents to incorporate two identical or different aryl groups into the ortho positions of benzaldehydes.

Regio- and Chemoselective Kumada-Tamao-Corriu Reaction of Aryl Alkyl Ethers Catalyzed by Chromium under Mild Conditions

Acting as an environmentally benign synthetic tool, the cross-coupling reactions with aryl ethers via C-O bond activation have attracted broad interest. However, the functionalizations of C-O bonds are mainly limited to nickel catalysis, and selectivity has long been a prominent challenge when several C-O bonds are present in the one molecule. We report here the first chromium-catalyzed selective cross-coupling reactions of aryl ethers with Grignard reagents by the cleavage of C-O(alkyl) bonds. Diverse transformations were achieved using simple, inexpensive chromium(II) precatalyst combining imino auxiliary at room temperature. It offers a new avenue for buildup functionalized aromatic aldehydes with high efficiency and selectivity.

Ruthenium complex catalyzed direct ortho arylation and alkenylation of aromatic imines with organic halides

Matrix presented The ortho position of the aromatic ring of imino group substituted aromatic compounds is directly arylated and alkenylated with organic halides in the presence of a catalytic amount of a ruthenium(II)-phosphine complex.