169836-01-5Relevant academic research and scientific papers
1-(phenylsulfonyl)indol-2-yl triflate: A versatile reagent for the synthesis of 2-substituted indoles
Joseph, Benoit,Malapel, Beatrice,Merour, Jean-Yves
, p. 3289 - 3295 (1996)
The palladium-catalysed reaction of 1-(phenylsulfonyl)indol-2-yl triflate 1 with a variety of aryl and heteroaryl boronic acids 2 or vinyl tributylstannane 3 provides a general and an efficient method for the synthesis of 2-substituted indoles 4.
Cyclic Allylamine-Enamine Systems. Part 8. Isomerisation Using Rhodium Complexes. 3-Aminoalkylidene-3H-indoles. Part 5. 6,7-Dihydroindoloquinolizine and 1,2,3,4,6,7-Hexahydroindoloquinolizine
Salas, Marisa,Al-Khawaja, Ibtisam K.,Thomas, Michelle J.,Joule, John A.
, p. 1666 - 1675 (2007/10/02)
The use of rhodium-complex catalysis for cyclic allylamine --> cyclic enamine isomerisation is described.Indoloquinolizines are produced using this methodology and also via 3-amino-3H-indole intermediates.N-alkylation of N-silylated amides is described.
