17016-65-8

Basic information

• Product Name: 3-(Benzoylamino)-2,3,6-trideoxy-D-lyxo-hexopyranose
• Synonyms: 3-(Benzoylamino)-2,3,6-trideoxy-D-lyxo-hexopyranose
• CAS NO: 17016-65-8
• Molecular Formula: C₁₃H₁₇NO₄
• Molecular Weight: 251.27838
• Mol File: 17016-65-8.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-(Benzoylamino)-2,3,6-trideoxy-D-lyxo-hexopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(Benzoylamino)-2,3,6-trideoxy-D-lyxo-hexopyranose(17016-65-8)
• EPA Substance Registry System: 3-(Benzoylamino)-2,3,6-trideoxy-D-lyxo-hexopyranose(17016-65-8)

Safety Data

• Hazardous Substances Data: 17016-65-8(Hazardous Substances Data)

Upstream product

• 62812-43-5 N-((2R,3S,4S,6R)-3-Hydroxy-6-methoxy-2-methyl-tetrahydro-pyran-4-yl)-benzamide 
• 58769-79-2 N-((2R,3S,4S,6S)-3-Hydroxy-6-methoxy-2-methyl-tetrahydro-pyran-4-yl)-benzamide 
• 100-46-9 benzylamine 
• 67315-16-6 methyl (4S,5S)-(4,5)-epoxy-2(E)-hexenoate 
• 98-88-4 benzoyl chloride 
• 102147-63-7 ((4R,5R,6S)-6-Methyl-2-oxo-5-triethylsilanyloxy-[1,3]oxazinan-4-yl)-acetic acid ethyl ester 
• 102147-61-5 (E)-(4R,5S)-5-Carbamoyloxy-4-triethylsilanyloxy-hex-2-enoic acid ethyl ester 
• 100689-24-5 (E)-(4R,5S)-5-Carbamoyloxy-4-hydroxy-hex-2-enoic acid ethyl ester 
• 102147-68-2 ethyl (+/-)-erythro-4-t-butoxy-5-hydroxy-trans-hex-2-enoate 
• 84173-36-4 (E)-ethyl 3-((2RS,3RS)-3-methyloxiran-2-yl) acrylate 
• 2396-84-1 (2E,4E)-ethyl hexa-2,4-dienoate 
• 110079-85-1 N-(xylo-5,6-epoxyhept-1-en-4-yl)trichloroacetamide 
• 110079-86-2 *,S^*),5(R^*,S^*)>-2-(trichloromethyl)-4-(1-prop-2-enyl)-5-<1(S^*,R^*)-hydroxyethyl>-2-oxazoline 
• 89179-22-6 E-hepta-3,6-dien-2-ol 

Relevant articles and documents

Synthesis of N-Bz-protected D-daunosamine and D-Ristosamine by silica gel promoted intramolecular conjugate addition of trichloroacetimidates obtained from osmundalactone and its epimer

Trichloroacetimidates prepared from osmundalactone and its epimer unexpectedly undergo intramolecular conjugate addition during silica gel chromatography to produce oxazolines in excellent yields. The novel, simple synthesis of N-Bz-protected D-daunosamin

Total syntheses of N-trifluoroacetyl-L-daunosamine, N-trifluoroacetyl-L-acosamine, N-benzoyl-D-acosamine, and N-benzoyl-D-ristosamine from an achiral precursor, methyl sorbate

A conjugated addition of benzylamine to methyl (4R,5S)-4,5-(isopropylidenedioxy)-(2E)-hexenoate (12) followed by lactonization under acidic condition proceeds formally to the total syntheses of L-daunasamine (1) and L-acosamine (2). On the other hand, direct conjugated addition of benzylamine to methyl (4S,5S)-4,5-epoxy-(2E)-hexenoate (4) and the subsequent intramolecular nucleophilic attack by ester carbonyl group against epoxy ring of the substrates leads to the formal total syntheses of D-acosamine (2) and D-ristosamine (3).

Stereochemistry of the Epoxidations of Acyclic Allylic Amides. Applications toward the Synthesis of 2,3,6-Trideoxy-3-aminohexoses

The stereochemistry of the epoxidation of several acyclic allylic amides is described.Diastereoselectivity in the (Z)-allylic amide series (compound 1) proved to be dependent both on the amide functionality and epoxidation reagent.The threo epoxide 3 was