170169-75-2

Basic information

• Product Name: 2-phenylseleno-1-trimethylsilyloxy-cyclohexene
• CAS NO: 170169-75-2
• Molecular Weight: 325.385
• Mol File: 170169-75-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-phenylseleno-1-trimethylsilyloxy-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenylseleno-1-trimethylsilyloxy-cyclohexene(170169-75-2)
• EPA Substance Registry System: 2-phenylseleno-1-trimethylsilyloxy-cyclohexene(170169-75-2)

Safety Data

• Hazardous Substances Data: 170169-75-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 50984-16-2 rac-2-(phenylseleno)cyclohexanone 

Downstream Products

• 14370-82-2 allyl phenyl selenide 
• 50984-16-2 rac-2-(phenylseleno)cyclohexanone 

Relevant articles and documents

Preparation of Silyl Enol Ethers Derived from α-Phenylseleno aldehydes and α-Phenylseleno ketones

The best experimental conditions for the preparation of trimethylsilyl enol ethers 3 from α-phenylseleno aldehydes 1, compatible with a limited deselenenylation of the substrate, were studied.Starting from α-phenylseleno ketones 2, the enoxysilanes 4, bearing a vinylic PhSe group, are the major products when triethylamine is the base.Trimethylsilyl enol ethers 5 with an allylic PhSe group are also formed beside 4 when LDA or KH are used at lower temperatures.