1702-18-7Relevant articles and documents
Preparation method of 2, 3-dichloro-6-cyanopyridine
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Paragraph 0025-0026; 0043-0065, (2020/05/08)
The invention discloses a preparation method of 2, 3-dichloro-6-cyanopyridine, and the method comprises the following steps: by using a metal chloride salt as a catalyst and phosphorus halide as a cocatalyst, carrying out one-step liquid-phase chlorination reaction on raw materials 2-chloro-6-cyanopyridine and chlorine to obtain 2, 3-dichloro-6-cyanopyridine; wherein the metal chloride salt is selected from at least one of WCl6, MoCl5, FeCl3, AlCl3, CuCl2, ZnCl2, RuCl3, SnCl4 and SbCl5, and the cocatalyst is selected from at least one of phosphorus pentachloride, phosphorus trichloride, phosphorus pentabromide and phosphorus tribromide. The method is simple in reaction process, low in production cost and high in target product selectivity and yield, the yield is 90% or above by optimizingreaction conditions, and the method has a good industrial prospect.
N-(phenylsulfonyl)picolinamide derivatives, process for producing the same, and herbicide
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, (2008/06/13)
A herbicide containing as the active ingredient an N-(henylsulfonyl)picolinamide derivative represented by general formula (I) wherein X reprcsents a halogeno, a C1-4 alkyl, a C1-4 haloalkyl, a C1-4 alkoxy, a C1-4 haloalkoxy, a (C1-4 alkoxy)carbonyl, a [di(C1-4 alkyl)amino]sulfonyl, an [N—(C1-4 alkyl)-N—(C1-4 alkoxy)amino]sulfonyl, a (C1-4 alkylamino)sulfonyl, a C1-4 alkylthio, a C1-4 alkylsulfinyl, a C1-4 alkylsulfonyl, or nitro; n is an integer of 0 to 5; Y represets a halogeno, a C1-4 alkyl, a C1-4 haloalkyl, a C1-4 alkoxy, C1-4 haloalkoxy, a C1-4 alkylthio, a C1-4 haloalkylthio, amino, a C1-4 alkylamino, a di(C1-4 alkyl)amino, a (C1-4 alkoxy) C1-4 alkyl, a (C1-4 alkylthio) C1-4 alkyl, or nitro; and m is an integer of 0 to 4. This active ingredient is synthesized by condensing a substituted picolinic acid with a substituted benzenesulfonamide under dehydration, or by reacting the phenyl ester of a substituted picolinic acid with a substituted benzenesulfonamide in the presence of a basic compound.
6-phenoxy picolinic acid alkylidene hydrazide derivative, process for producing the same and herbicide using the same
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, (2008/06/13)
PCT No. PCT/JP98/02842 Sec. 371 Date Feb. 23, 2000 Sec. 102(e) Date Feb. 23, 2000 PCT Filed Jun. 25, 1998 PCT Pub. No. WO99/00370 PCT Pub. Date Jan. 7, 1999A 6-phenoxy picolinic acid alkylidene hydrazide derivative, a process for producing the derivative and a herbicide containing the derivative as an effective ingredient. Such a compound is a novel compound and is useful as an effective ingredient of herbicides.