170303-18-1

Basic information

• Product Name: Ethanone, 1-[2-(2-methyl-1-propenyl)cyclopropyl]-, cis- (9CI)
• Synonyms: Ethanone, 1-[2-(2-methyl-1-propenyl)cyclopropyl]-, cis- (9CI)
• CAS NO: 170303-18-1
• Molecular Formula: C9H14O
• Molecular Weight: 138.20686
• Product Categories: ACETYLGROUP
• Mol File: 170303-18-1.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-[2-(2-methyl-1-propenyl)cyclopropyl]-, cis- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[2-(2-methyl-1-propenyl)cyclopropyl]-, cis- (9CI)(170303-18-1)
• EPA Substance Registry System: Ethanone, 1-[2-(2-methyl-1-propenyl)cyclopropyl]-, cis- (9CI)(170303-18-1)

Safety Data

• Hazardous Substances Data: 170303-18-1(Hazardous Substances Data)

Upstream product

• 13949-93-4 (+/-)-ethyl trans-2-formyl-1-cyclopropanecarboxylate 
• 16647-04-4 6-methylhepta-3,5-dien-2-one 
• 1774-47-6 trimethylsulfoxonium iodide 
• 38996-77-9 (+/-)-ethyl trans-2-(2-methyl-1-propenyl)cyclopropane-carboxylate 
• 53166-51-1 (+/-)-trans-2-(2-methyl-1-propenyl)cyclpopropanecarboxylic acid 
• 3999-55-1 diethyl trans-cyclopropane-1,2-dicarboxylate 
• 31420-66-3 (±)-trans-2-(ethoxycarbonyl)cyclopropanecarboxylic acid 
• 15224-11-0 ethyl (1S*,2S*)-2-(hydroxymethyl)cyclopropane-1-carboxylate 
• 75-16-1 methylmagnesium bromide 

Relevant articles and documents

Gold-catalyzed cycloisomerization of cyclopropyl alkynyl acetates: A versatile approach to 5-, 6-, and 7-membered carbocycles

Nonclassical chirality transfer? Depending on the substitution pattern of propargyl acetates, a gold-catalyzed homologous Rautenstrauch reaction generates either 5- or 6-membered ring systems (see scheme). The stabilization of cationic intermediates is crucial for this reaction to succeed. The underlying principle for the good chirality transfer observed could be gold-stabilized nonclassical carbocations having configurational stability.