170461-84-4Relevant academic research and scientific papers
Synthesis of planar-chiral cobalticinium complexes
Komatsuzaki, Nobuko,Uno, Mitsunari,Shirai, Kazuhiko,Tanaka, Takanori,Sawada, Masami,Takahashi, Shigetoshi
, p. 53 - 62 (1995)
Planar-chiral cobalticinium complexes having a carboxylic function were synthesized in an enantiomerically pure form and transformed into several derivatives such as amide, ester and alcohol.The molecular structure including absolute configuration of 8b was established by a single-crystal X-ray structure analysis.Based on the configuration of the (-)-menthyl group, the absolute configuration of 8b around the Cp-M moiety was determined to be R.Keywords: Cobalt; Cyclopentadienyl; Optical resolution; X-ray diffraction; Chirality
