17067-71-9Relevant articles and documents
Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives
Dilman, Alexander D.,Arkhipov, Dmitry E.,Korlyukov, Alexander A.,Ananikov, Valentine P.,Danilenko, Vitalij M.,Tartakovsky, Vladimir A.
, p. 3680 - 3689 (2007/10/03)
A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5) 3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The cr
Phenylation of Organic Derivatives of Mercury, Silicon, Tin, and Bismuth with Pentaphenylantimony and Pentaphenylphosphorus
Sharutin,Sharutina,Senchurin,Egorova,Ivanenko,Petrov
, p. 202 - 203 (2007/10/03)
Pentaphenylantimony and -phosphorus react with arylmercury chlorides in toluene at room temperature to give diaryl derivatives of mercury in yields of up to 95%. The reactions of pentaphenylantimony and -phosphorus with silicon and tin halides involve ary
Preparation of halogeno(pentafluorophenyl)silanes (C6F5)nSiX4-n (X=F, Cl and Br; N=2, 3) from pentafluorophenyl(phenyl)silanes (C6F5)nSiPh4-n
Frohn,Lewin,Bardin
, p. 233 - 240 (2007/10/03)
Halogeno(pentafluorophenyl)silanes (C6F5)nSiX4-n (X=F, Cl and Br; n=2, 3) were prepared in good yields from the corresponding phenylsilanes (C6F5)nSiPh4-n by reactions with the electrophiles aHF, FSO3H, HCl-AlCl3 or with AlX3 (X=Cl, Br)-halogenated hydrocarbons. The relative leaving ability of the organyl groups (C6F5, C6H5, Me) bonded to the silicon atom and the strength of the electrophilic reagent are discussed.
