17082-47-2Relevant articles and documents
Studies on the synthesis and thermal properties of alkoxysilane-terminated organosilicone dendrimers
Saxena, Kanak,Bisaria,Saxena
, p. 251 - 256 (2010)
Silicone core dendrimers bearing terminaldialkoxy andtrialkoxy silane groups were prepared in a three-step synthesis. Initially, the Si-H terminated multifunctional silicone dendrimer, i.e. tetrakis(dimethylsiloxy)silane, was prepared by the reaction of tetraethoxysilane and dimethylethoxysilane. Tetrakis(dimethylsiloxy)silane on reaction with allylglycidylether in the presence of Speier's catalystunderpressure (100 psi) yieldedepoxy- terminateddendrimerin veryhigh yield (95%).Theepoxy-terminated dendrimer was reacted with aminopropylalkoxysilanes to yield the next-generation dendrimer bearing dialkoxy and trialkoxy silane groups. The dendrimers were characterized by the usual physico-chemical techniques, i.e. elemental analysis, FT-IR, 1H, 13C and 29Si NMR. Thermal studies (Thermogravimetric analysis and Thermomechanical analysis) of the alkoxy terminated dendrimers and its cured products were also carried out. Copyright
Preparation of branched siloxane
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Page/Page column 16, (2010/02/10)
By reacting a branched siloxane compound of formula (2) containing compounds of formula (1) as an impurity with a disiloxane compound of formula (3) in the presence of an acid compound, there is prepared a branched siloxane of formula (2) containing a reduced level of compounds of formula (1).R1?nSi(OSiR2?3)3-n(OR3)R1?nSi(OSiR2?3)4-nR2?3SiOSiR2?3 R1 is a monovalent hydrocarbon group, R2 and R3 are H or monovalent hydrocarbon groups, and n is 0 or 1.
SYNTHESIS OF TETRAKIS(DIMETHYLSILOXY)- AND TETRAKIS(DIMETHYLORGANYLSILOXY)SILANES
Kalmychkov, G. V.,Yarosch, N. K.,Mirskov, R. G.,Voronkov, M. G.,Rakhlin, V. I.
, p. 590 (2007/10/02)
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