170941-62-5Relevant academic research and scientific papers
Preparation of a stable trifluoroborate salt for the synthesis of 1-aryl-2,2-difluoro-enolethers and/or 2,2-difluoro-1-aryl-ketones via palladium-mediated cross-coupling
Katz, Jason D.,Lapointe, Blair T.,Dinsmore, Christopher J.
experimental part, p. 8866 - 8869 (2010/03/02)
(Chemical Equation Presented) A bench-stable potassium trifluoroborate enol ether reagent has been prepared. This reagent is suitable for the incorporation of 2,2-difluoroenolethers into aryl and heteroaryl systems via palladium-mediated cross-coupling wi
Generating diversity in difluoromethyl ketone derivatives
DeBoos, Gareth A.,Fullbrook, Jeremy J.,Percy, Jonathan M.
, p. 2859 - 2861 (2007/10/03)
(equation presented) Two consecutive palladium-catalyzed coupling reactions from a readily available difluoroenol stannane set the stage for the synthesis of a range of difluoro-and halodifluoromethyl ketones upon a variable aryl template.
