170951-65-2Relevant academic research and scientific papers
Ligand exchange reaction of sulfoxides in organic synthesis: A novel method for synthesizing acetylenes and allenes from carbonyl compounds through sulfoxides having a trifluoromethanesulfonyloxy group on the β-carbon
Satoh, Tsuyoshi,Itoh, Norifumi,Watanabe, Shizue,Koike, Hirofumi,Matsuno, Haruko,Matsuda, Kenji,Yamakawa, Koji
, p. 9327 - 9338 (2007/10/02)
A novel method for synthesizing acetylenes and allenes from carbonyl compounds is described. Ligand exchange reaction of alkenylsulfoxides having a trifluoromethanesulfonyloxy group on the β-carbon, which were derived from α-alkyl β-ketosulfoxides, with n
Ligand Exchange Reaction of Sulfoxides in Organic Synthesis. A Novel Method for Synthesizing Acetylenes from Carbonyl Compounds through β-Trifluoromethanesulfonyloxy Vinyl Sulfoxides
Satoh, Tsuyoshi,Itoh, Norifumi,Watanabe, Shizue,Matsuno, Haruko,Yamakawa, Koji
, p. 567 - 570 (2007/10/02)
α-Sulfinyl ketones were prepared by the reaction of alkyl phenyl sulfoxide or chloromethyl p-tolyl sulfoxide with aldehydes or methyl esters in high yields, and were converted to acetylenes through β-trifluoromethanesulfonyloxy vinyl sulfoxides by the lig
