17099-23-9

Basic information

• Product Name: Benzenamine, N-[(3-chlorophenyl)methylene]-4-methoxy-
• CAS NO: 17099-23-9
• Molecular Formula: C14H12ClNO
• Molecular Weight: 245.708
• Mol File: 17099-23-9.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-[(3-chlorophenyl)methylene]-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-[(3-chlorophenyl)methylene]-4-methoxy-(17099-23-9)
• EPA Substance Registry System: Benzenamine, N-[(3-chlorophenyl)methylene]-4-methoxy-(17099-23-9)

Safety Data

• Hazardous Substances Data: 17099-23-9(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 587-04-2 m-Chlorobenzaldehyde 
• 18951-47-8 (E)-4-<2-(3-chlorophenyl)ethenyl>phenol 
• 2101-87-3 p-methoxy-phenylazide 
• 2039-85-2 3-Chlorostyrene 

Downstream Products

• 587-04-2 m-Chlorobenzaldehyde 
• 501-58-6 (E)-1,2-bis(4-methoxyphenyl)diazene 
• 1009565-42-7 2-(3-chlorophenyl)-3-fluoro-6-methoxy-4-(trifluoromethyl)quinoline 
• 1039451-66-5 (2E,5S)-ethyl 5-(4-methoxyphenylamino)-5-(3-chlorophenyl)-pent-2-enoate 
• 1061672-29-4 (2E,5R)-5-(4-methoxyphenylamino)-5-(3-chlorophenyl)-1-(piperidin-1-yl)pent-2-en-1-one 
• 1133378-58-1 (2S,3S)-2-(3-chlorophenyl)-1-(4-methoxyphenyl)-1,2,3,4-tetrahydropyridine-3-carbaldehyde 
• 1221718-00-8 C₂₁H₂₄ClNO₃ 
• 861039-28-3 2-(3-chlorophenyl)-6-methoxyquinoline 
• 1245135-97-0 2-(3-chlorophenyl)-1-(4-methoxyphenyl)-2,3-dihydropyridin-4(1H)-one 
• 1309440-25-2 benzyl 1-(methoxycarbonyl)-2-(4-methoxyphenylamino)-2-(3-chlorophenyl)-1-phenylethylcarbamate 
• 1309440-20-7 benzyl 1-(methoxycarbonyl)-2-(4-methoxyphenylamino)-2-(3-chlorophenyl)-1-p-tolylethylcarbamate 
• 1326705-10-5 (1S,2S)-N-(4-methoxyphenyl)-1-(3-chlorophenyl)-2-(methylsulfenyl)-2-{2-[(S)-p-tolylsulfinyl]phenyl}ethylamine 
• 1335242-79-9 C₂₂H₁₇ClN₂ 

Relevant articles and documents

Copper-Catalyzed Intramolecular Amination of C(sp3)-H Bond of Secondary Amines to Access Azacycles

The cross-coupling of C-N bond directly from inert C-H bonds is an ideal approach to synthesize saturated azacycles due to its high efficiency and atom economy. In this article, a copper-catalyzed intramolecular amination via the cross coupling of C(sp3)-H and N-H bonds of secondary amine has been reported, which exhibit excellent chemo- and regioselectivity, extensive substrate scope, and functional group tolerance in good to excellent yield, offering an efficient pathway to build nitrogen-containing heterocycle skeletons.

Tert-Butyl Hydroperoxide-Mediated Oxo-Sulfonylation of 2 H-Indazoles with Sulfinic Acid toward Indazol-3(2 H)-ones

A new and efficient oxo-sulfonylation protocol has been established for the synthesis of N-sulfonylated indazolones employing sulfinic acid as a sulfonylating agent using tert-butyl hydroperoxide (TBHP) under ambient air. A series of structurally diverse 1-sulfonylindazol-3(2H)-one derivatives were obtained in good yields. A radical reaction mechanism has been proposed for this transformation.

Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via C=C Bond Cleavage

C=C bond breaking to access the C=N bond remains an underdeveloped area. A new protocol for C=C bond cleavage of alkenes under nonoxidative conditions to produce imines via an iron-catalyzed nitrene transfer reaction of 4-hydroxystilbenes with aryl azides is reported. The success of various sequential one-pot reactions reveals that the good compatibility of this method makes it very attractive for synthetic applications. On the basis of experimental observations, a plausible reaction mechanism is also proposed.