171081-02-0

Basic information

• Product Name: 4-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2-iodo-3-methoxyphenyl trifluoromethanesulfonate
• Synonyms: 4-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2-iodo-3-methoxyphenyl trifluoromethanesulfonate
• CAS NO: 171081-02-0
• Molecular Weight: 692.492
• Mol File: 171081-02-0.mol

Chemical Properties

• CAS DataBase Reference: 4-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2-iodo-3-methoxyphenyl trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2-iodo-3-methoxyphenyl trifluoromethanesulfonate(171081-02-0)
• EPA Substance Registry System: 4-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2-iodo-3-methoxyphenyl trifluoromethanesulfonate(171081-02-0)

Safety Data

• Hazardous Substances Data: 171081-02-0(Hazardous Substances Data)

Upstream product

• 171081-06-4 3-(tert-butyldiphenylsilyloxy)-2-iodo-1-(methoxymethoxy)benzene 
• 171080-98-1 3-(tert-butyldiphenylsilyloxy)-2-iodophenol 
• 121980-53-8 2-iodo-3-(methoxymethoxy)phenol 
• 358-23-6 trifluoromethylsulfonic anhydride 

Downstream Products

• 171081-04-2 6-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-5-methoxy-1,4-naphthoquinone 
• 171081-05-3 2-chloro-6-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-5-methoxy-1,4-naphthoquinone 
• 314280-46-1 4-((2R,4R,5R,6R)-4,5-Bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,8-dimethoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-one 

Relevant articles and documents

C-glycosyl juglone in angucycline synthesis: Total synthesis of galtamycinone, common aglycon of C-glycosyl naphthacenequinone-type angucyclines

A two-step access to C-glycosyl juglones, 16 and 17, useful intermediates toward the angucyclines, either benz[a]anthraquinone- type or naphthacenequinone-type, has been developed based on (1) the O→C-glycoside rearrangement and (2) the regioselective cycloaddition of α-alkoxybenzyne and α-oxyfuran. The first total synthesis of galtamycinone (2), the common aglycon of naphthacenequinone-type angucyclines, has been achieved by utilizing 17 as the key intermediate.

C-Glucosylation-Cycloaddition Approach to C-Glycosyl Juglones. Versatile Intermediates toward Aryl C-Glycoside Antibiotics

An efficient two-step access to C-glycosyl juglones promising synthetic intermediates toward aryl C-glycoside antibiotics, has been developed based on (1) the O->C-glycoside rearrangement and (2) the regioselective cycloaddition of α-alkoxybenzyne and α-oxyfuran.