121980-53-8Relevant academic research and scientific papers
Total synthesis of the gilvocarcins
Hosoya, Takamitsu,Takashiro, Eiji,Matsumoto, Takashi,Suzuki, Keisuke
, p. 1004 - 1015 (2007/10/02)
Convergent total syntheses of the aryl C-glycoside antibiotics gilvocarcin M (1a) and gilvocarcin V (1b) have been accomplished. Key steps include (1) contrasteric coupling of D-fucofuranosyl acetate 27 with iodophenol 26, which was achieved by employing
ARYL RADICAL-INDUCED CYCLIZATION ROUTES TO FUROBENZOFURANS. ABBREVIATED FORMAL SYNTHESES OF AFLATOXINS B1 AND B2
Sloan, C. P.,Cuevas, J. C.,Quesnelle, C.,Snieckus, V.
, p. 4685 - 4686 (2007/10/02)
Radical-induced cyclization of butenolide ethers 3a-c affords furobenzofurans 4a-c; deprotection of 4c gives 4d, thus concluding formal total syntheses of aflatoxins B1 (5) and B2 (6).
