171083-36-6

Basic information

• Product Name: (S)-N,N'-Di-p-tolyl-tetrahydro-pyrrolo<2,1-c><1,4>oxazin-3,4-diylidendiamin
• CAS NO: 171083-36-6
• Molecular Weight: 333.433
• Mol File: 171083-36-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-N,N'-Di-p-tolyl-tetrahydro-pyrrolo<2,1-c><1,4>oxazin-3,4-diylidendiamin(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N,N'-Di-p-tolyl-tetrahydro-pyrrolo<2,1-c><1,4>oxazin-3,4-diylidendiamin(171083-36-6)
• EPA Substance Registry System: (S)-N,N'-Di-p-tolyl-tetrahydro-pyrrolo<2,1-c><1,4>oxazin-3,4-diylidendiamin(171083-36-6)

Safety Data

• Hazardous Substances Data: 171083-36-6(Hazardous Substances Data)

Upstream product

• 7472-70-0 N,N'-bis(4-methylphenyl)ethanediimidoyl dichloride 
• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 

Relevant articles and documents

On the Aminolysis of Bis-Imidoylchlorides of Oxalic Acid. II. Reaction with Aliphatic Diamines and Aminoalcohols

The aminolysis of bis-imidoylchloride 1 derived from oxalic acid with several diamines and aminoalcohols was investigated.At room temperature diamines 2 as well as aminoalcohols 7 give mainly the cyclic amidines 3 and mixed amidine-imidates 8 in moderately up to good yields.While cis-1,2-diaminocyclohexane yields at room temperature the bicyclic amidine 3a, the trans isomer reacts to 3b only when heated for several hours.Depending on the conditions, the racemic 1,2-diaminopropane 2h gives derivatives of pyrazine 3h or the open-chain amidine 5 resulting from an oxidative aromatization and subsequent hydrolysis.Histamine 2i and 1,8-diamino-3,6-dioxaoctane 2p react selectively with 1 to seven- respectively twelve-membered heterocycles 3i and 3p.The mixed aliphatic and aromatic diamines 2n, o show an anomalous behaviour leading to 2,2'-bis-chinazolines 3n, o.In comparison with acyclic oxalic amidines the new cyclic derivatives show less molecular dynemic in their nmr spectra.In some cases, a s-trans-arrangement of the amidine substructure was observed.