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1711-10-0

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1711-10-0 Usage

General Description

3-Iodobenzoyl chloride is a chemical compound that belongs to the class of organic compounds known as benzoic acid and derivatives. Its systematic name is 3-Iodobenzenecarbonyl chloride and it is identified by CAS number 6189-48-0. It appears as a white to yellow crystalline solid with a molecular weight of 292.42 g/mol. The compound is used in chemical synthesis processes, particularly in the production of other organic compounds. One of the major safety considerations is its reactivity with water and alcohols to produce corrosive hydrochloric acid, therefore, it should be carefully handled and stored.

Check Digit Verification of cas no

The CAS Registry Mumber 1711-10-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,1 and 1 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1711-10:
(6*1)+(5*7)+(4*1)+(3*1)+(2*1)+(1*0)=50
50 % 10 = 0
So 1711-10-0 is a valid CAS Registry Number.
InChI:InChI=1/C7H4ClIO/c8-7(10)5-2-1-3-6(9)4-5/h1-4H

1711-10-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Iodobenzoyl Chloride

1.2 Other means of identification

Product number -
Other names 3-IODOBENZOYL CHLORIDE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1711-10-0 SDS

1711-10-0Relevant articles and documents

Thiophene Modulated BODIPY Dye as a Light Harvester

Li, Xiaochuan,Liao, Meifei,Sun, Jia,Heo, Gisu,Son, Young-A

, p. 127 - 136 (2019)

A new BODIPY dye with terthiophene branched is configured by Sonogashira coupling and fully characterized by NMR and MS. In general organic solvents, it emits typical green fluorescence ranging in 513-518 nm, like most BODIPY analogues. The terthiophene substitution is greatly improved and the emission peak does not sensitive to the polarity environment. More importantly, the terthiophene plays the role of antenna, harvesting the 340 nm’s excitation energy and transferring the energy to BODIPY efficiently. Even though the molar extinction coefficient in 340 nm is lower than that of maximum absorption, it can enlarge the pseudo Stoke’s shift to ~170 nm, well separating the excitation and emission. In film, the emission shifted to 562 nm due to the polymer chain dissipation part of the energy. It shifted further to 585 nm in solid. The branched terthiophene configures a twisted molecular conformation, which avoids the dye regular packing. Highly emission, excellent solubility and stability constitute the general character of the thiophene attached BIDIPY dye.

-

Norris,Young

, p. 1420,1424 (1935)

-

Synthesis and radioiodination of some 9-aminoacridine derivatives

Ghirmai, Senait,Mume, Eskender,Henssen, Cecile,Ghaneolhusseini, Hadi,Lundqvist, Hans,Tolmachev, Vladimir,Sjoeberg, Stefan,Orlova, Anna

, p. 3719 - 3725 (2004)

Derivatives of 9-aminoacridine, namely N-[ω-(acridin-9-yl-amino) alkyl]-3-(trimethylstannyl)benzamides (1), where the alkyl group is propyl (1a) and octyl (1b), and 2-(acridin-9-ylamino)-3-(4-hydroxyphenyl)propionic acid (2), have been synthesized with the aim to use them as precursors in the syntheses of radiolabeled DNA intercalators for biological experiments. It was observed that compounds 1a and 1b can exist in two isomeric forms at room temperature. Radioiodination of the two benzamides 1a and 1b was carried out with the Auger-emitting nuclide 125I by exchange of the trimethylstannyl group. The optimal conditions for radioiodination of the octyl derivative 1b were established and the labeling yield was found to be as high as 92%, according to TLC analysis in model experiments. Purification of the radioiodinated products gave radiochemical yields of 56% for the propyl and 74% for the octyl compound. The amino acid 2 was directly labeled with 125I at the ortho position to the hydroxyl group by taking advantage of the activated ring. The experiment afforded a very high labeling yield (92%). Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Nickel-mediated C(sp2)-H amidation in synthesis of secondary sulfonamides via sulfonyl azides as amino source

Xu, Peng,Ding, Peng-Fei,Zhang, Mei-Qi,Xia, Yu-Shi,Xie, Ting

supporting information, (2021/02/16)

In this paper, Ni(II)- Catalyzed ortho-amidation of C(sp2)-H bond with sulfonyl azides directed by (quinolin-8-yl) amine (AQ-amine) is described. The method provides a straightforward method for the synthesis of sulfonamides from available sulfonyl azides via the transition-metal-catalyzed C(sp2)-N bond forming reaction. The amidation reactions exhibit high functional group compatibility, which might proceed a Ni(III)/Ni(I) catalytic cycle. We also applied sulfonamide compound in OLEDs, which exhibits the certain application potential in OLEDs field.

Synthesis of N-trifluoromethyl amides from carboxylic acids

Flavell, Robert R.,Liu, Jianbo,Parker, Matthew F. L.,Toste, F. Dean,Wang, Sinan,Wilson, David M.

supporting information, p. 2245 - 2255 (2021/08/12)

Found in biomolecules, pharmaceuticals, and agrochemicals, amide-containing molecules are ubiquitous in nature, and their derivatization represents a significant methodological goal in fluorine chemistry. Trifluoromethyl amides have emerged as important functional groups frequently found in pharmaceutical compounds. To date, there is no strategy for synthesizing N-trifluoromethyl amides from abundant organic carboxylic acid derivatives, which are ideal starting materials in amide synthesis. Here, we report the synthesis of N-trifluoromethyl amides from carboxylic acid halides and esters under mild conditions via isothiocyanates in the presence of silver fluoride at room temperature. Through this strategy, isothiocyanates are desulfurized with AgF, and then the formed derivative is acylated to afford N-trifluoromethyl amides, including previously inaccessible structures. This method shows broad scope, provides a platform for rapidly generating N-trifluoromethyl amides by virtue of the diversity and availability of both reaction partners, and should find application in the modification of advanced intermediates.

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