171182-88-0Relevant articles and documents
Tris[(1H,1H,2H,2H-perfluoroalkyl) aryl]phoshites and catalytic uses thereof
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, (2008/06/13)
A method for preparing tris[(1H,1H,2H,2H-perfluoroalkyl)aryl]phosphites consists in preparing a grignard reagent from an alkoxyhalogenobenzene, then reacting it with a iodo-1H,1H,2H,2H-perfluoroalkane; transforming the alkoxy function of (1H,1H,2H,2H,2H-perfluoroalkyl)alkoxybenzene obtained into a hydroxy function, then reacting (1H,1H,2H,2H-perfluoroalkyl)hydroxybenzene with PCl3. The invention also concerns fluorinated arylphosphites and their use as transition metal ligand for making catalysts to be used in two-phase catalysis with fluorinated phase.