171285-94-2

Basic information

• Product Name: (1R,2R)-2-azido-2,3-dihydro-1H-inden-1-yl-4-nitrobenzoate
• Synonyms: (1R,2R)-2-azido-2,3-dihydro-1H-inden-1-yl-4-nitrobenzoate
• CAS NO: 171285-94-2
• Molecular Weight: 324.296
• Mol File: 171285-94-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,2R)-2-azido-2,3-dihydro-1H-inden-1-yl-4-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R)-2-azido-2,3-dihydro-1H-inden-1-yl-4-nitrobenzoate(171285-94-2)
• EPA Substance Registry System: (1R,2R)-2-azido-2,3-dihydro-1H-inden-1-yl-4-nitrobenzoate(171285-94-2)

Safety Data

• Hazardous Substances Data: 171285-94-2(Hazardous Substances Data)

Upstream product

• 166942-30-9 (1S,2R)-2-azido-2,3-dihydro-1H-inden1-ol 
• 62-23-7 4-nitro-benzoic acid 

Downstream Products

• 119-65-3 isoquinoline 
• 13575-72-9 (1R,2R)-trans-2-amino-1-indanol 

Relevant articles and documents

Concurrent Formation of N-H Imines and Carbonyl Compounds by Ruthenium-Catalyzed C-C Bond Cleavage of β-Hydroxy Azides

A commercial cyclopentadienylrutenium dicarbonyl dimer ([CpRu(CO)2]2) efficiently catalyzes the formation of N-H imines and carbonyl compounds simultaneously from β-hydroxy azides via C-C bond cleavage under visible light. Density functional theory calculations for the cleavage reaction support the mechanism involving chelation of alkoxy azide species and liberation of nitrogen as the driving force. The synthetic utility of the reaction was demonstrated by a new amine synthesis promoted by chemoselective allylation of imine and synthesis of isoquinoline.