17136-56-0Relevant academic research and scientific papers
Biosynthesis of the N–N-Bond-Containing Compound l-Alanosine
Daniel-Ivad, Phillip,He, Hai-Yan,Niikura, Haruka,Ryan, Katherine S.,Wang, Menghua
supporting information, p. 3881 - 3885 (2020/02/04)
The formation of a N?N bond is a unique biochemical transformation, and nature employs diverse biosynthetic strategies to activate nitrogen for bond formation. Among molecules that contain a N?N bond, biosynthetic routes to diazeniumdiolates remain enigma
Process for producing N-alkylhydroxylamines
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, (2008/06/13)
A novel process for producing an N-alkylhydroxylamine of the formula (I) wherein R represents an alkyl group which may be substituted with least one substituent, which comprises reacting an N-mesyl-O-(p-alkoxybenzyl)hydroxylamine or an N-mesyl-O-(2,4,6-trialkylbenzyl)hydroxylamine with an alkyl halide of the formula (III) wherein R is as defined above and X represents a halogen atom, under a basic condition to produce the corresponding N-alkyl-N-mesyl-O-(p-alkoxybenzyl)hydroxylamine or N-alkyl-N-mesyl-O-(2,4,6-trialkylbenzyl)hydroxylamine, and treating the resulting compound with a solution of a phenol compound, and novel N-alkyl-N-mesyl-O-(p-alkoxybenzyl)hydroxyl amines and N-alkyl-N-mesyl-O-(2,4,6-trialkylbenzyl)hydroxylamines which are useful as intermediates in the above process.
