171523-96-9

Upstream product

• 171523-95-8 (2S,4'S)-2-<oxy>-1-<4'-(2'-phenyloxazolinyl)>-4-pentene 
• 102614-19-7 (4S)-4-(2'-Oxoethyl)-2-phenyloxazoline 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 130459-39-1 2-Phenyl-4(S)-(2(S)-hydroxypent-4-enyl)-2-oxazoline 

Downstream Products

• 130459-41-5 (2S,4S)-2-(N-Benzyl-N-methylamino)-4-<oxy>-6-hepten-1-ol 
• 171598-92-8 (2R,4S)-2,4-O-Isopropylidene-1-(phenylthio)-6-heptene-2-ol 
• 171523-99-2 (2R,4S)-4-<oxy>-1-(phenylthio)-6-hepten-2-ol 

Relevant academic research and scientific papers

Synthetic studies on the polyene macrolide antibiotics. Development of syn- and anti-1,3-diol subunits and assembly of the polyacetate region of amphotericin B

The synthesis of syn- and anti-1,3-diol subunits from thiol ester oxazoline 4 has been described. The key features of these synthetic sequences include the stereodivergent allylation of an asymmetric β-amino aldehyde (7) and the stereospecific transformat

Studies toward the application of oxazoline-epoxide equivalency in 1,3-asymmetric induction

Synthetically versatile epoxy alcohols have been prepared from a common intermediate, chiral aldehyde, through a sequence involving diastereoselective allylation followed by stereospecific transformation of the oxazoline to an epoxide.