171523-99-2

Upstream product

• 130481-49-1 (4S,6R)-4-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6,7-epoxy-1-heptene 
• 108-98-5 thiophenol 
• 130459-41-5 (2S,4S)-2-(N-Benzyl-N-methylamino)-4-<oxy>-6-hepten-1-ol 
• 171523-95-8 (2S,4'S)-2-<oxy>-1-<4'-(2'-phenyloxazolinyl)>-4-pentene 
• 171523-96-9 (2S,4'S)-2-(N-Benzylamino)-4-<oxy>-6-hepten-1-ol 
• 130459-39-1 2-Phenyl-4(S)-(2(S)-hydroxypent-4-enyl)-2-oxazoline 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 171598-92-8 (2R,4S)-2,4-O-Isopropylidene-1-(phenylthio)-6-heptene-2-ol 

Relevant academic research and scientific papers

Synthetic studies on the polyene macrolide antibiotics. Development of syn- and anti-1,3-diol subunits and assembly of the polyacetate region of amphotericin B

The synthesis of syn- and anti-1,3-diol subunits from thiol ester oxazoline 4 has been described. The key features of these synthetic sequences include the stereodivergent allylation of an asymmetric β-amino aldehyde (7) and the stereospecific transformat