171613-12-0

Basic information

• Product Name: 2,3,4-tri-O-benzoyl-α-L-xylopyranosyl trichloroacetimidate
• Synonyms: 2,3,4-tri-O-benzoyl-α-L-xylopyranosyl trichloroacetimidate
• CAS NO: 171613-12-0
• Molecular Weight: 606.844
• Mol File: 171613-12-0.mol

Chemical Properties

• CAS DataBase Reference: 2,3,4-tri-O-benzoyl-α-L-xylopyranosyl trichloroacetimidate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4-tri-O-benzoyl-α-L-xylopyranosyl trichloroacetimidate(171613-12-0)
• EPA Substance Registry System: 2,3,4-tri-O-benzoyl-α-L-xylopyranosyl trichloroacetimidate(171613-12-0)

Safety Data

• Hazardous Substances Data: 171613-12-0(Hazardous Substances Data)

Upstream product

• 171754-78-2 tetrabenzoyl-L-xylose 
• 98-88-4 benzoyl chloride 
• 87-72-9 L-xylopyranose 
• 545-06-2 trichloroacetonitrile 

Relevant articles and documents

Synthesis of a xylosylated rhamnose pentasaccharide - The repeating unit of the O-specific side chain of lipopolysaccharides from the reference strains for Stenotrophomonas maltophilia serogroup O18

A xylosylated rhamnose pentasaccharide, α-L-Rhap-(1→3)-[β-L-Xylp-(1→ 2)-] [β-L-Xylp-(1→4)-]α-L-Rhap-(1→3)-L-Rhap, the repeating unit of the O-specific side chain of the lipopolysaccharides from the reference strains for Stenotrophomonas maltophilia serogroup O18, was synthesized by a highly regio- and stereoselective procedure. Thus coupling of methyl rhamnopyranoside (9) with 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl trichloroacetimidate (8) gave the (1→3)-linked disaccharide (10), and subsequent benzoylation and deacetylation afforded the disaccharide acceptor 12. Condensation of 12 with 8 yielded methyl 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1→3)-α-L- rhamnopyranosyl-(1→3)-2,4-di-O-benzoyl-α-L-rhamnopyranoside (13). Coupling of 13 with 2,3,4-tri-O-benzoyl-α-L-xylopyranosyl trichloroacetimidate (4) followed by deprotection gave the target pentasaccharide (15).