171817-39-3 Usage
Uses
Used in Coordination Chemistry:
1-(dicyclohexylphosphino)-2-[1-(dimethylamino)ethyl]ferrocene is used as a ligand for stabilizing transition metal complexes, which is crucial for the development of new catalysts and the study of metal coordination environments.
Used in Catalysis Reactions:
In the field of catalysis, 1-(dicyclohexylphosphino)-2-[1-(dimethylamino)ethyl]ferrocene is used as a ligand to enhance the efficiency and selectivity of various chemical transformations, taking advantage of its steric and electronic properties to fine-tune the catalytic activity.
Used in Organic Synthesis:
1-(dicyclohexylphosphino)-2-[1-(dimethylamino)ethyl]ferrocene is employed as a reagent in organic synthesis to facilitate specific reactions, such as cross-coupling or hydrogenation, where its unique structural features can improve the yield and selectivity of the desired products.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, given its role in catalysis and coordination chemistry, 1-(dicyclohexylphosphino)-2-[1-(dimethylamino)ethyl]ferrocene could potentially be used in the pharmaceutical industry for the development of new drugs, where its ability to stabilize metal complexes could be leveraged in the synthesis of complex organic molecules with therapeutic potential.
Used in Materials Science:
In materials science, 1-(dicyclohexylphosphino)-2-[1-(dimethylamino)ethyl]ferrocene may be utilized in the design and synthesis of new materials with specific properties, such as conductivity or catalytic activity, by incorporating its metal complexes into the material's structure.
Check Digit Verification of cas no
The CAS Registry Mumber 171817-39-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,1,8,1 and 7 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 171817-39:
(8*1)+(7*7)+(6*1)+(5*8)+(4*1)+(3*7)+(2*3)+(1*9)=143
143 % 10 = 3
So 171817-39-3 is a valid CAS Registry Number.
171817-39-3Relevant academic research and scientific papers
Grugel, Christian P.,Breit, Bernhard
, p. 15223 - 15226 (2018)
A rhodium-catalyzed regio- and enantioselective intermolecular allylation of malononitriles as masked acyl cyanides (MAC) with terminal and symmetrical internal allenes is reported. A RhI/Josiphos catalytic system combined with subsequent oxidative degradation of the primary adducts enables a straightforward access to α-branched, β,γ-unsaturated carbonyl compounds. The present protocol exhibits perfect atom economy in the allylation step and is characterized by a great functional group compatibility. Furthermore, the use of α-substituted malononitriles allowed for the construction of all-carbon quaternary centers.
Synthesis of new derivatives of copper complexes of Josiphos family ligands for applications in asymmetric catalysis
Oost,Rong,Minnaard,Harutyunyan
, p. 1997 - 2005 (2014/06/24)
A series of new copper complexes containing chiral ferrocenyl diphosphine ligands of the Josiphos family have been prepared. These complexes have been studied in the catalytic asymmetric 1,2-addition of Grignard reagents to enones and aromatic ketones. Variation of the electronic and steric properties of the ligand resulted in a positive effect in the regio- and enantioselectivity of Grignard reagents to α-H-substituted enones using the ligand in which tert-butyl substituents were introduced in the diarylphosphine moiety. The copper complexes were also successfully applied in the catalytic asymmetric conjugate addition of Grignard reagents to enoates. No increase of enantioselectivity was observed in the catalytic asymmetric addition of linear Grignard reagents, compared to that of the commercially available ligand rev-Josiphos. The Royal Society of Chemistry 2014.
