171818-80-7

Basic information

• Product Name: Os₃(CO)10(P(C₆H₅)3)(NCCH₃)
• CAS NO: 171818-80-7
• Molecular Weight: 1154.05
• Mol File: 171818-80-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Os₃(CO)10(P(C₆H₅)3)(NCCH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: Os₃(CO)10(P(C₆H₅)3)(NCCH₃)(171818-80-7)
• EPA Substance Registry System: Os₃(CO)10(P(C₆H₅)3)(NCCH₃)(171818-80-7)

Safety Data

• Hazardous Substances Data: 171818-80-7(Hazardous Substances Data)

Upstream product

• 116261-58-6 Os₃(CO)₁₁(PPh₃) 
• 75-05-8 acetonitrile 

Downstream Products

• 116261-58-6 Os₃(CO)₁₁(PPh₃) 

Relevant articles and documents

REACTIVITY OF (M = Ru, Os) TOWARDS ORGANIC AND ORGANOMETALLIC ELECTROPHILES; EVIDENCE FOR ELECTROPHILIC endo-ATTACK AT THE PHOSPHIDO MOIETY OF

Electrophilic attack on the bridging phosphido moiety of (1) allows the formation of new phosphorus-containing compounds.The phosphido clusters (R = (CH2)6I (2a), (CH2)10I (2b), C4H8OH (2c), HOs3(CO)10(PPh3) (4a), HOs3(CO)10 (4b) have been synthesized by the reaction of 1 with the appropriate electrophiles.When R = alkyl, both exo- and endo-isomers are formed.The formation of both isomers indicates that endo-attack plays a significant role in these reactions.When R = (μ-H)Os3(CO)10(PR3) the exo-isomers are the exclusive products.Reaction of the ruthenium analogue of 1 with leads to the formation of 4-P)> (6).The crystal structure of (μ3-PH)> (4b) is presented.Key words: Phosphido moiety, cluster, Osmium, Ruthenium, electrophilic attack, isomer.