171867-02-0

Basic information

• Product Name: Methyl α-azido-2-<(2E,4E)-4-(p-nitrophenyl)buta-1,3-dienyl>cinnamate
• CAS NO: 171867-02-0
• Molecular Weight: 376.371
• Mol File: 171867-02-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl α-azido-2-<(2E,4E)-4-(p-nitrophenyl)buta-1,3-dienyl>cinnamate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl α-azido-2-<(2E,4E)-4-(p-nitrophenyl)buta-1,3-dienyl>cinnamate(171867-02-0)
• EPA Substance Registry System: Methyl α-azido-2-<(2E,4E)-4-(p-nitrophenyl)buta-1,3-dienyl>cinnamate(171867-02-0)

Safety Data

• Hazardous Substances Data: 171867-02-0(Hazardous Substances Data)

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 59259-01-7 2-<2-(1,3-dioxolanyl)>benzaldehyde 
• 7743-31-9 <3-(4-Nitrophenyl)-2-propenyl>triphenylphosphoniumbromid 
• 1816-92-8 Methyl azidoacetate 
• 171732-81-3 2-[(1E,3E)-4-(4-Nitro-phenyl)-buta-1,3-dienyl]-benzaldehyde 

Downstream Products

• 134272-10-9 (1S,8R,9S)-9-(4-Nitro-phenyl)-12-aza-tricyclo[6.3.2.0^2,7]trideca-2,4,6,10,12-pentaene-13-carboxylic acid methyl ester 

Relevant articles and documents

On the Formation of N-Heterocycles by Thermolysis of Conjugated α-Azidoacrylates

The synthesis of various o-butadienyl-α-azidocinnamates 2 and β-cycloalkenyl-α-azidoacrylates 9 is described.The thermolysis of compounds 2 in solution yields the new 8,9-benzo-6-azabicyclonona-3,6,8-trienes 3 as major products, while that of 9 yields the cycloalkano-2H-pyrroles 10, which can rearrange to the cycloalkano-1H-pyrroles 11 at higher temperatures.A β-(o-vinyl)phenanthryl-α-azidoacrylate 12 was found to react on thermolysis both as a β-cycloalkenyl-α-azidoacrylate and a o-vinyl-α-azidocinnamate. - Keywords: α-Azidoacrylates, thermolysis of / α-Azidocinnamates, thermolysis of / 1H-Pyrroles / 2H-Pyrroles