171977-31-4Relevant articles and documents
Tetraphenylantimony aroxides Ph4SbOAr (Ar = C6H4C6H7, C6H2(Br2-2,6)(tert-Bu-4), C6H3(NO2)2-2,4, C6H2(Br2-2,6)(NO2-4)): Synthesis and structure
Sharutin,Sharutina,Senchurin
, p. 295 - 300 (2017)
Tetraphenylantimony aroxides Ph4SbOAr, where Ar = C6H4C6H7 (I), C6H2(Br2-2,6)(tert-Bu-4) (II), C6H2(Br2-2,6)(NO2-4) (III), and C6H3(NO2)2-2,4 (IV), have been synthesized by the reaction of pentaphenylantimony with 4-cyclohexadienylphenol, 2,6-dibromo-4-tert-butylphenol, 2,6-dibromo-4-nitrophenol, and 2,4-dinitrophenol. The antimony atoms in molecules of complexes I–IV have a differently distorted trigonal bipyramidal coordination to the oxygen atoms of aroxy groups in axial positions. The OSbС angles are 177.63(13)° (I), 174.29(7)° (II), 177.8(6)° (III), and 174.01(7)° (IV). The Sb–O bond length is 2.117(3) ? (I), 2.2613(15) ? (II), 2.409(11) ? (III), and 2.4296(15) ? (IV).
Synthesis, structure, and thermal destruction of aroxytetraphenylstiboranes
Sharutin, V. V.,Zhidkov, V. V.,Muslin, D. V.,Liapina, N. Sh.,Fukin, G. K.,et al.
, p. 931 - 936 (2007/10/02)
A series of aroxytetraphenylstiboranes, Ph4SbOAr, were obtained by the reaction of pentaphenylstiborane with phenols at ca.20 deg C.The thermolysis of these compounds gives O- or o-C-phenylation products.The thermolysis of stiboranes, which incorporate aryl groups containing electron-withdrawing substituents (Ar = 2,4-Br2, 2,4-Cl2, 2-NO2, 4-OPh) produces predominantly simple diaryl ethers of asymmetric structure in 58percent, 90percent, 32percent, and 60percent yields, respectively.