172217-59-3Relevant academic research and scientific papers
METHOD FOR THE PREPARATION OF alpha-SUBSTITUTED ACRYL ALDEHYDES
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Paragraph 0098; 0099; 0100, (2016/04/19)
The invention discloses simple and rapid method for the preparation of α-substituted acryl aldehydes. More particularly, the invention discloses a method for the preparation of α-substituted acryl aldehydes via a gold-catalysed [1,3] rearrangement of the allenyl ethers with a record turnover frequency of 4600 h?1 at 0.05 mol % of the catalyst concentration in homogeneous gold(I) catalysis. The α-substituted acryl aldehydes synthesized by the instant process are used as building blocks in organic synthesis.
Gold(i)-catalysed [1,3] O→C rearrangement of allenyl ethers
Kona, Chandrababu Naidu,Ramana, Chepuri V.
supporting information, p. 2152 - 2154 (2014/02/14)
A simple and rapid access to the α-substituted acryl aldehydes has been provided by developing a gold-catalysed [1,3] rearrangement of the allenyl ethers importantly with a record turnover frequency of 4600 h-1 (at 0.05 mol% of the catalyst concentration) in homogeneous gold(i) catalysis. The Royal Society of Chemistry.
