75168-42-2Relevant academic research and scientific papers
Syntheses of Trifluoroethylated N-Heterocycles from Vinyl Azides and Togni's Reagent Involving 1, n-Hydrogen-Atom Transfer Reactions
Bolm, Carsten,Meister, Daniela,Petran, Benedict,Rissanen, Kari,Terhorst, Steven,Tiwari, Deo Prakash
supporting information, (2020/06/29)
2,2,2-Trifluoroethyl-substituted 3-oxazolines, 3-thiazolines, and 5,6-dihydro-2H-1,3-oxazines have been obtained by reacting substituted vinyl azides with a combination of Togni's reagent and substoichiometric amounts of iron(II) chloride. The results of
Cyclopropanation of Benzene Rings by Oxidatively Generated α-Oxo Gold Carbene: One-Pot Access to Tetrahydropyranone-Fused Cycloheptatrienes from Propargyl Benzyl Ethers
Ji, Kegong,Zhang, Liming
supporting information, p. 647 - 651 (2017/12/26)
Cyclopropanations of benzene rings by oxidatively generated α-oxo gold carbenes are for the first time demonstrated in a Buchner reaction, in which readily available propargyl benzyl ethers are converted in one-pot to tetrahydropyranone-fused cycloheptatrienes via sequential oxidative gold catalysis and base-promoted isomerization. Additional examples of arene cyclopropanations without fragmentation of the cyclopropane ring are also realized. (Figure presented.).
PROPARGYL α-PHENYLETHYL ETHER AND ITS DERIVATIVES
Karaev, S. F.,Dzhafarov, D. S.,Askerov, M. E.
, p. 809 - 813 (2007/10/02)
Propargyl α-phenylethyl ether was obtained from phenylmagnesium bromide and α-chloroethyl propargyl ether.Hydration, aminomethylation, and reactions with ethylene glycol and organosilanes were carried out with the product.A Iotsich reagent was obtained from propargyl α-phenylethyl ether and was used in reactions with acetone, triorganochlorosilanes, and chloromethyl propargyl ether.
