172226-07-2Relevant academic research and scientific papers
Reactions of C-H bonds in organic oxygenates with octaethylporphyrinato rhodium(II) and iridium(II) dimers
Rossi, Kenneth J. Del,Zhang, Xiao-Xiang,Wayland, Brandford B.
, p. 47 - 56 (2007/10/03)
Metalloporphyrin dimers, 2 (1a, M - Rh; 1b, M = Ir; OEP = octaethylporphyrin dianion), are observed to react with C-H bond units in aldehydes, ketones and benzyl alcohols.Aldehydes, R2CHCHO, preferentially react at the alkyl group adjacent to the
