172228-59-0Relevant articles and documents
Iridium-promoted conversion of chlorosilanes to alkynyl derivatives in a one-pot reaction sequence
Kownacki, Ireneusz,Orwat, Bartosz,Marciniec, Bogdan
supporting information, p. 3051 - 3059 (2014/07/08)
By making use of the catalytic potential of the iridium system [{Ir(μ-Cl)(CO)2}2]/NEt(i-Pr)2 in the synthesis of silyl-functionalized alkynes via silylative coupling of terminal alkynes/diynes with iodosilanes, we propose
An efficient and simple method for the preparation of symmetrical disiloxanes from hydrosilanes by Lewis acid-catalyzed air oxidation
Sridhar, Madabhushi,Ramanaiah, Beeram China,Narsaiah, Chinthala,Kumara Swamy, Mudam,Mahesh, Bellam,Kumar Reddy, Mallu Kishore
experimental part, p. 7166 - 7168 (2010/02/27)
Symmetrical disiloxanes were prepared in high yields by air oxidation of mono, di, and trihydrosilanes under Lewis acid catalysis.
Highly selective oxidation of organosilanes to silanols with hydrogen peroxide catalyzed by a lacunary polyoxotungstate
Ishimoto, Ryo,Kamata, Keigo,Mizuno, Noritaka
supporting information; experimental part, p. 8900 - 8904 (2010/01/16)
Silanol synthesis: Divacant lacunary polyoxotungstate (nBu4N+)4[g- SiW10O34(H2O)2] (I) is an efficient homogeneous catalyst for highly selective oxidation of organosilanes to silanols with 30/60% aqueous H2O2. Various kinds of silanes 1 containing aryl, alkyl, alkenyl, alkynyl and alkoxy groups are chemoselectively converted into the corresponding silanols 2 in high yields with only one equivalent of aqueous H2O2 with respect to the substrate.
A convenient synthesis of alkynylsilanes by silylation of copper(I) alkynides
Sugita, Hikaru,Hatanaka, Yasuo,Hiyama, Tamejiro
, p. 379 - 380 (2007/10/03)
Alkynylation of chlorosilanes with copper(I) alkynides takes place smoothly in the presence of triphenylphosphine, N, N, N′, N′-tetramethylethylenediamine, or zinc powder to give a variety of alkynylsilanes in good yields.